As an obstacle against the widespread application of membranes in larger scales, fouling via different materials could cause a severe decline in water permeation. Herein, we fabricated a novel mechanically-stable electro-conductive membrane by simple pressure-assisted laminating of reduced Graphene Oxide-Polyaniline (rGO-PANI) suspension on the commercial polyethersulfone (PES) support layers. Field emission scanning electron microscopy (FESEM) and water contact angle measurements were used to characterize rGO-PANI membranes. Using PANI improved the mechanical stability of laminated film and reduced the water contact angle, making a more hydrophilic surface. Organic fouling behaviors of newly fabricated membranes were also investigated by applying a DC voltage to membranes. The experimental results showed a significant improvement in water flux recovery when 2 V DC potential is applied on the surface of the rGO-PANI membrane.