Nitrogen co-doped with fluorine on reduced graphene oxide (rGO) was prepared by one-pot hydrothermal treatment method. The scanning electron microscopy (SEM) images and X-ray photoelectron microscopy (XPS) spectra revealed the successful doping of nitrogen and fluorine into the rGO. The Brunauer-Emmett-Teller (BET) results demonstrated high surface area of N-F-rGO that are favorable for oxygen adsorption. The results show that N-F-rGO catalyst has improved the catalytic performance electrode for the ORR in alkaline environment than the fluorine undoped N-rGO. The Koutechy-Levich (KL) analysis and rotating ring disk electrode (RRDE) measurements suggest that N-F-rGO dominantly favors a 4e- reduction process. The nitrogen co-doped with fluorine on rGO exhibited remarkable long-term stability towards the ORR than Pt/C. These improved electrochemical properties indicate that N-F-rGO will be a promising candidate for cost-effective electrode material for application of non-polluting alternative energy sources.